There are different roads you can go with the crossover filter components.
It is my point of view the original parts, particularly the caps of the crossover now are old and worn, and from a lower quality as a good cap from today.
Adding a modern high quality small bypass cap to the existing caps should already give an increase in sound quality, taken that the old ribbon can reproduce that.
Replacing all caps and resistors for newer and better should definitely give a better sound. That is what I will do with my Calipers.
The choice of caps may give different accents in the experience of the sound. It does to me, while others have reported to them it didn't make much difference. Each of it's own there.
On the newly capped crossover, it is possible to add a little 'flavor' in the form of a e.g. top notch bypass cap. This similar to the use of a tiny bit of truffles in the kitchen.
It is my experience though the added bypass cap comes at the price of a slightly less 3-dimensionality of the sound. I guess for the simple reason they are different from the base caps. Anyway for my Centaurs I have accepted this. My plan for the Calipers is to keep it at one single type of caps.
Here is a nice site with comparisons of caps. Take with a grain of salt and as a rough guide. Your experience with a cap may be different. After all, only you have your pair of ears.
But e.g. after reading I applied a Jantzen Superior bypass in the crossovers of the simple Mission speakers I use with my TV-set and I fully agree with the author they are dead neutral.
Currently my Calipers are still crated. All kinds of issues, tragedies and priorities have kept me from getting them done so far.
With your Duettas you are incredibly lucky to have acquired them leave alone for that money. Long time ago my own stupidity kept me from getting a pair in about the same circumstances as you got yours.
Many sellers overestimate the value of Apogee speakers because they look good and have a reputation and they don't want to see how the parts have deteriorated and ignore the costs of getting them back into a good condition.
I can hear very quickly the difference between multitracks recording's lack of natural and the live jazz or classical perfect positioning of instruments and vocals...
I also like jazz and many recordings have been direct mastered and that is what adds to the natural sound they have.
If you hear those differences you have a good pair of ears and a wonderful pair of speakers worth saving up to having them restored to their very best standard!
About the measured values of your Duetta crossover, I think to know old Apogee wasn't always very precise with what they put into it.